Experimental Lineage and Functional Analysis of a Remotely Directed Peptide Epoxidation Catalyst
نویسندگان
چکیده
منابع مشابه
Experimental Lineage and Functional Analysis of a Remotely Directed Peptide Epoxidation Catalyst
We describe mechanistic investigations of a catalyst (1) that leads to selective epoxidation of farnesol at the 6,7-position, remote from the hydroxyl directing group. The experimental lineage of peptide 1 and a number of resin-bound peptide analogues were examined to reveal the importance of four N-terminal residues. We examined the selectivity of truncated analogues to find that a trimer is s...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2014
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja410567a